The number of possible arrangements of a standard 52-card deck is 52 factorial, written with 68 digits. It is so large that even the most dramatic comparisons strain to capture it. The estimated number of atoms in the Milky Way is vastly smaller. After around seven riffle shuffles a deck is genuinely randomized, meaning every properly shuffled deck is almost certainly in an arrangement that has never existed before and will never exist again.
Daniel and Mom work through what 52 factorial actually means, why the galaxy comparison is not hyperbole, what seven shuffles does mathematically, and how to hold a number too large for ordinary human intuition. The episode closes on Mom sending Daniel to go create something the universe has never seen.

Daniel is nine. He asks the questions, refuses to accept easy answers, and picks every episode topic himself.

Mom does the digging - finding the sources, checking the claims, and translating them into something a nine-year-old will actually sit still for.
A deck of 52 cards can be arranged in 52 factorial ways. Written out, that number has 68 digits.
The number of arrangements vastly exceeds the estimated number of atoms in the Milky Way galaxy.
After about seven riffle shuffles a deck is genuinely randomized rather than just mixed.
Every properly shuffled deck is almost certainly in an arrangement that has never existed before.
“Go ahead. You will almost certainly create something that has never existed before.”